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논문 해외 국제전문학술지(SCI급) Crosslinkable polyhedral silsesquioxane-based ceramic-coated separators for Li-ion batteries

Crosslinkable polyhedral silsesquioxane-based ceramic-coated separators for Li-ion batteries
  • 학술지 구분 국제전문학술지(SCI급)
  • 게재년월 2019-03
  • 저자명 유명현,전현규,노영준,진다희,정용철,이용민
  • 학술지명 JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
  • 발행처명 ELSEVIER SCIENCE INC
  • 발행국가 해외
  • 논문언어 외국어
  • 전체저자수 6
  • 논문 다운로드 링크(외부) https://doi.org/10.1016/j.jiec.2018.11.036
  • 연구분야 공학 > 화학공학

논문 초록 (Abstract)

Inorganic polyhedral oligomeric silsesquioxane with epoxy functional groups (ePOSS) is newly presented as a co-binder for the ceramic-coated separator (CCS) for safe Li-ion batteries. The ePOSS-incorporated coating layer significantly improved the dimensional stability of the CCS at 140 degrees C and maintained the original form even after an ignition test. Although the permeability of the CCS was slightly decreased due to the crosslinked structure of the silsesquioxane coating layer, it showed high electrochemical stability up to 5 V. Moreover, the improved liquid electrolyte wettability by ePOSS co-binder enhanced the ionic conductivity and showed 93% of cycle capacity at 0.5C rate in Li-ion batteries. (C) 2018 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.